Potential problems with conventional austenitic stainless steels
While some austenitic stainless steels such as 316L and 316LN are currently utilised in superconducting magnets there is a concern that many of the products manufactured from these grades do not possess a stable, single-phase austenitic microstructure. These conventional alloys contain a percentage of the ferrite phase content and demonstrate a susceptibility to strain-induced martensitic transformation, particularly at cryogenic temperatures and under high mechanical stresses – two of the primary engineering challenges associated with HTS magnet systems.
When this transformation occurs, the alloy's austenite phase converts into a ferromagnetic martensite phase, causing significant changes to the material's magnetic properties - the steel's magnetic permeability increases. In superconducting magnet systems, this can distort the magnetic field required for plasma containment and affect the stability and precision of the HTS coils.
Additionally, the material's ductility and fracture toughness is reduced which is a major cause for concern in cryogenic applications. At these low temperatures, martensitic phases are more prone to cracking and loss of ductility can compromise the structural integrity of components under stress.
Conventional grades containing Niobium, Vanadium or Titanium
Conventional grades of austenitic stainless steels that intentionally contain elements including Niobium, Vanadium or Titanium should not be considered as optimum for use in nuclear fusion applications as these elements promote precipitation within the microstructure, also adversely affecting ductility, toughness and suitability for use at cryogenic temperatures.
Furthermore, this would change the composition of the matrix locally in the vicinity of these precipitates, leading to impoverishment of certain critical elements which adversely affects the performance of these grades.
It is also clear that such conventional stainless steels would not possess a single-phase austenitic microstructure, potentially leading to strain-induced martensitic transformation.